I'm surprising that you had such problems, actually. When I went to Google and searched for Buy "Jessica Simpson" clothes the matches weren't great, but the sponsored and advertised sites offered the following:
A bit further down is this tantalizing snippet:
" Coming soon to a Wal-Mart near you: Jessica Simpson's clothing line."
That suggests that visiting Wal-Mart would be valuable, so that's what I did next. A search for "Jessica Simpson" on that site, however, only gave us matches in Books, Music and Movies.
Okay, not good. Time for a different approach. I went back to Google and looked for a magazine or newspaper that focuses on the apparel industry. A quick search of "apparel news newsletter clothing" ironically revealed that Yahoo had a terrific directory of these publications: Apparel: News and Media: Trade Magazines.
Still with me?
I recognized one of the publications, Women's Wear Daily, so popped over to that site. My goal: to see if they have any reports of what Simpson's selling and through whom. A bit more digging and we find:
"Earlier this month, JS brand management, which holds The master License For The Jessica Simpson and Sweet Kisses brands"
So now let's go one further step and see if we can find JS Brand Management on Google! In fact, the very first match from a search for "JS Brand Management" is this article: USA : Jessica Simpson & JS Brand Management to launch fashion apparel brand - Sweet Kisses at MAGIC.
Okay. FINALLY we have the name of the clothing line: Sweet Kisses. Back to Google again, this time to see who carries this clothing line.
The bad news? After all that digging, all I can find is that Sweet Kisses is also the name of one of her albums, which means that it's all confused and mixed together. My guess? You can't yet actually buy any of Simpson's Sweet Kisses clothing: if you could I think it'd be a lot easier to find some results.
I'd just pop over to the Jessica Simpson "official site" and keep an eye on the news there, or, even better, join the Jessica Simpson Fan Club.
Hope this helps you out. Sorry I couldn't offer a better answer!
Update! Turns out a pal of mine does have a better answer and suggests both of these sites for you: JessicaStyle.com and About.com: Teen Style.
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Bought a pair of Jessica Simpson pants at Dillards on the clearance rack and LOVE them. Target does not carry her clothes and Dillards were getting rid of her brand. The other website was just a site that you could buy stuff that she has worn but not her clothes...I too, would love to know where I could buy her clothes. I love the fit!